Ag掺杂p型ZnO薄膜及其光电性能研究

采用超声喷雾热分解法在石英衬底上以醋酸锌水溶液为前驱体,以硝酸银水溶液为Ag掺杂源生长了Ag掺杂ZnO(ZnO：Ag)薄膜.研究了衬底温度对所得ZnO：Ag薄膜的晶体结构、电学和光学性质的影响规律.所得ZnO：Ag薄膜结构良好,在室温光致发光谱中检测到很强的近带边紫外发光峰,透射光谱中观测到非常陡峭的紫外吸收截止边和较高的可见光区透过率,表明薄膜具有较高的晶体质量与较好的光学特性.霍尔效应测试表明,在500℃下获得了p型导电的ZnO：Ag薄膜,载流子浓度为5.30×10¹⁵cm关键词： ZnO：Ag薄膜 p型掺杂 超声喷雾热分解 霍尔效应     

基于内嵌钴/氮掺杂多孔碳三维石墨烯笼的抗团聚高效氧还原电催化剂

氧还原反应是决定燃料电池、金属-空气电池等多种新型清洁能源存储与转化技术之性能与应用的关键反应. 铂及其合金是目前催化活性最好的氧还原反应催化剂,但其高昂的成本限制了规模化应用. 在小尺寸效应作用下,微纳米结构催化剂颗粒在电极制备与电化学反应过程中的团聚限制了催化剂本征催化活性的充分发挥. 本文基于喷雾热解技术,发展了一种基于内嵌钴/氮掺杂多孔碳三维石墨烯笼的高活性、抗团聚非贵金属氧还原反应催化剂. 此结构中,金属有机骨架化合物ZIF-67衍生的钴/氮掺杂多孔碳纳米结构是催化氧还原反应的活性中心,包覆其外的三维石墨烯笼不仅可在钴/氮掺杂碳纳米结构之间构建连续的三维载流子传导网络,且可高效抑制其在催化剂制备与电化学反应过程中的团聚与活性损失. 在碱性电解液中,此类非贵金属催化剂表现出可与铂基催化剂媲美的氧还原反应活性和优异的稳定性.     

阶梯型加速段对旋流喷嘴雾化特性的影响

旋流内芯是压力旋流式喷嘴最主要的旋流发生构件, 其几何特征直接影响压力旋流式喷嘴的喷雾特性.目前采用平滑型加速段的旋流内芯导流效率较低.为减小高流量条件下的能量损失, 使喷嘴旋流内芯加速段对喷雾介质产生预旋效应, 增强旋流强度, 本文设计喷嘴旋流内芯加速段为阶梯型, 其下段阶梯相对上段阶梯旋转15°, 旋向与喷嘴旋流槽方向相同.利用粒子动态分析仪(particle dynamics analysis system, PDA) 和高速摄影(charge coupled device, CCD)系统实验研究了加速段结构改进前后喷嘴的喷雾流量、雾场索特尔平均直径(Sauter mean diameter, SMD)、雾滴速度以及喷雾锥角, 并分析了SMD、 雾滴速度的轴向和径向分布特性. 结果表明, 背压差0.08\mathrm{~} 0.46 MPa 范围内, 阶梯型加速段对喷雾介质具有较好的预旋效果.喷嘴的流量提高了48.0% ~ 51.8%; 喷雾的轴向速度提升了31.4% ~ 32.8%, 径向速度提升了1.6% ~ 16.8%; 喷雾锥角减小了4.21°~6.57°; 较高背压差下喷雾下游的SMD减小了9.8%.与平滑型加速段相比, 阶梯型加速段的设计有效地提高了喷嘴的雾化质量.      

Numerical investigation of droplet pre-dispersion in a monodisperse droplet spray dryer

Monodisperse droplet spray dryers have great advantages in particle formation through spray drying because of their ability to produce uniform sized particles. Experimental analyses of this system have shown that droplets atomized through the piezoceramic nozzle need to be sufficiently well dispersed before entering the drying chamber to achieve sufficiently dried particles. However, the dispersion dynamics cannot be readily observed because of experimental limitations, and key factors influencing the dispersion state currently remain unclear. This study carried out numerical simulations for droplet dispersions in the dispersion chamber, which allow this important process to be visualized. The systematic and quantitative analyses on the dispersion states provide valuable data for improving the design of the dispersion chamber, and optimizing the spray drying operation.     

A STUDY ON DROPLET VELOCITY OF ETHANOL DURING ELECTROSPRAYING PROCESS AT CONE-JET MODE

研究液滴在静电喷雾下的速度特性是理解喷雾形态的形成及演化的关键.结合锥射流模式下乙醇静电喷雾实验数据,建立了静电喷雾二维轴对称模型.基于离散相液滴运动方程、连续相空气运动方程、电场方程以及用户自定义函数,进行了数值求解,获得了锥射流模式下的乙醇静电喷雾形态、空间电场分布以及液滴速度场分布.考虑了不同空气入口流速的影响,得到了乙醇/空气同轴射流静电喷雾形态的变化规律.结果表明,喷雾外围液滴与空气流场有较强的相互作用,导致喷雾中轴线附近的液滴速度分布变化较小,而在喷雾外围处的液滴速度分布沿径向剧烈变化;随着空气入口速度的增大,乙醇/空气同轴射流静电喷雾形态先趋于发散,当空气入口速度大于喷雾外围液滴轴向速度时,喷雾形态则趋于聚拢.因此,除改变施加电压、液体流量和电极结构外,通过控制空气入口速度来影响喷雾液滴速度场,也可获得不同的静电喷雾效果.     

聚合物/蒙脱土纳米复合乳液的制备及其表面施胶性能

采用蒙脱土(MMT)改性聚苯乙烯-丙烯酸酯(PSB)乳液制备了一种新型表面施胶剂。 比较了不同方法合成的乳液在性能上的异同。 采用X射线衍射（XRD）和透射电子显微镜（TEM）测试技术表征了复合材料的结构。 研究了苯丙/蒙脱土纳米复合乳液作为表面施胶剂对纸张的物理性能和抗水性能的影响。 结果表明,聚合法制备的复合乳液中蒙脱土片层已发生剥离并在复合物中呈现纳米级分散。 纳米复合乳液与淀粉以质量比1∶10（绝干）复配进行表面施胶时,纸张的施胶度、挺度和环压强度比纯苯丙施胶剂分别提高1.8倍、45.5%和44%。     

Application of the scale entropy diffusion model to describe a liquid atomization process

Whatever the situation, liquid atomization processes show a continuous evolution of the liquid system shape. However, such a system is a multiscale object, i.e., its shape cannot be fully described by a single geometrical parameter. The present work makes use of the scale entropy function to describe this multiscale object. This function is found similar to the scale distribution previously introduced to take into account the droplet shape in liquid spray characterization. Time-averaged scale entropy is locally measured on images of atomizing liquid flows issuing from a low injection pressure single-hole triple-disk nozzle. The advantage in using this nozzle is that the atomization process and the spray are inscribed in a plane and can be fully described by 2-D visualizations. The measurements are performed from the nozzle exit down to the spray region. The operating conditions consider varying injection pressure and liquid physical properties. The temporal evolution of the scale entropy is described by the scale entropy diffusion model. Initially developed in turbulence, this model introduces new parameters such as the scale diffusivity and the local scale entropy flux sink, which characterize the diffusion dynamic of the scale entropy in the scale space. For the first time, these parameters are measured and strong correlations between them and the working conditions are evidenced. Furthermore, new parameters are introduced such as a scale viscosity and the total scale entropy flux lose. These results demonstrate the relevance of the scale entropy diffusion model to describe a liquid atomization process. This application is the first of its kind.     

射流损失---小孔型脉冲管制冷机的一种重要损

脉冲管冷端和热端的层流化元件是脉冲管制冷机的重要部分。本文从流体力学、热力学出发,分析了小孔型脉冲管热端的流动过程和热力过程,确定了小孔型脉冲管的制冷机理。在此基础上,分析表明在脉冲管热端存在射流现象和涡流现象,导致一种气流混合的损失。本文称之为射流损失。设计了几种改进结构,实验验证了这种损失的存在同时也揭示了改进方法的有效性。     

喷嘴雾化特性实验研究

液体雾化是当前两相流研究中非常重要的课题,在农业、能源以及环境工程中具有广泛的应用价值,进行深入系统的研究具有重要意义。本文以空气、水为工质,使用马尔文粒度仪对单相和两相雾化器喷嘴的雾化特性进行了比较实验研究。测量了不同压力配比条件下液体雾化粒子的粒径分布,详细讨论了压力对于喷嘴雾化效果的影响。同时得出了两相流量与压力之间的变化规律。     

Numerical simulation of flow in Hartmann resonance tube and flow in ultrasonic gas atomizer

The gas flow in the Hartmann resonance tube is numerically investigated by the finite volume method based on the Roe solver.The oscillation of the flow is studied with the presence of a needle actuator set along the nozzle axis.Numerical results agree well with the theoretical and experimental results available.Numerical results indicate that the resonance mode of the resonance tube will switch by means of removing or adding the actuator.The gas flow in the ultrasonic gas atomization (USGA) nozzle is also studied by the same numerical methods.Oscillation caused by the Hartmann resonance tube structure,coupled with a secondary resonator,in the USGA nozzle is investigated.Effects of the variation of parameters on the oscillation are studied.The mechanism of the transition of subsonic flow to supersonic flow in the USGA nozzle is also discussed based on numerical results.